Synthesis and Characterization of Amido and Amido(Monoalkylamido)Nitrosyl-[Tris(3,5-Dimethylpyrazolyl)Borato]Molybdenum Complexes
Open Access
- 1 September 1997
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 27 (8) , 1205-1217
- https://doi.org/10.1080/00945719708000258
Abstract
The chloro-amido complex [Mo{HB(3,5-Me2C3HN2)3} (NO)C1(NH2)] was prepared by treating [Mo{HB(3,5-Me2C3HN2)3} (NO)Cl2] with an excess of ammonia. The monoalkylamido complexes [Mo{HB(3,5-Me2C3HN2)3}-(NO)(NH2)(NHR)] (R = Me, Et, Pr-n and Bu-n were obtained by the reaction of [Mo{HB(3,5-Me2C3HN2)3} (NO)C1(NH2)] with the appropriate primary amines. The IR and 1H NMR spectra of the new complexes were investigated.Keywords
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