The formation of amine and amide complexes in the reactions between [Mo(NO){HB(3,5-Me2C3N2H)3}X2] (X = Cl or I) and saturated cyclic amines. The molecular structures of [Mo(NO){HB(3,5-Me2C3N2H)3}I(NHC5H10)] and [Mo(NO){HB(3,5-Me2C3N2H)3}I(NC4H8)]
- 1 January 1988
- journal article
- Published by Elsevier in Polyhedron
- Vol. 7 (19-20) , 1931-1938
- https://doi.org/10.1016/s0277-5387(00)80707-x
Abstract
No abstract availableKeywords
This publication has 11 references indexed in Scilit:
- Monometallic, homo- and hetero-bimetallic complexes based on redox active tris(3,5-dimethylpyrazolyl)borato molybdenum and tungsten nitrosyls. Part 6. Synthesis and electrochemistry of complexes containing saturated heterocyclic amide ligands. X-Ray crystal and molecular structure of [{Mo(NO)[HB(Me2pz)3]Cl}2(NC4H8N)]J. Chem. Soc., Dalton Trans., 1987
- Molybdenum and tungsten nitrosyl complexes containing bulky alkoxy, aryloxy, and arylamido ligands: their electrochemical behaviour and the structure of [Mo{HB(Me2pz)3}(NO)I(OCH2CH2CH2Br)]J. Chem. Soc., Dalton Trans., 1986
- Dicarbonylnitrosyl{Tris(3,5‐Dimethylpyrazolyl)Hydroborato}‐ Molybdenum(III) and Iodo‐, Alkoxy‐, and Alkylamido‐Molybdenum(III) DerivativesPublished by Wiley ,1985
- Electrochemical and chemical properties of di-iodonitrosyl[tris(3,5-dimethylpyrazolyl)borato]molybdenum, [Mo{HB(Me2pz)3}(NO)I2], and related complexesJ. Chem. Soc., Dalton Trans., 1985
- Steric and electronic effects on the chemistry of molybdenum octahedrally co-ordinated by six nitrogen atoms. The molecular structure of [Mo{HB(3,5-Me2C3N2H)3}(NO)(pyrollide)2]Journal of the Chemical Society, Chemical Communications, 1984
- Tilden Lecture. Alkoxy, amido, hydrazido, and related compounds of molybdenum and tungstenChemical Society Reviews, 1983
- Arylamido and aryloxy complexes of nitrosyl[tris(3,5-dimethylpyrazolyl)borato]molybdenum, some mixed alkoxy/aryloxy and aryloxy/monoalkylamido species, and the structures of [Mo{HB(3,5-Me2C3N2H)3}(NO)I(NHC6H4R-p)](R = Me and OMe)J. Chem. Soc., Dalton Trans., 1983
- The synthesis and structure of bis(acetonitrile)nitrosyl tris(3,5-dimethylpyrazolyl)borato molybdenum hexafluorophosphateTransition Metal Chemistry, 1982
- Nitrosyl complexes of molybdenum and tungsten. Part 15. Iodo(monoalkylamido)nitrosyl[tris(3,5-dimethylpyrazolyl)borato]molybdenum complexes, some related tungsten compounds, and the crystal and molecular structure of ethylamido(iodo)nitrosyl[tris(3,5-dimethyl-pyrazolyl) borato]molybdenumJ. Chem. Soc., Dalton Trans., 1982
- Remarkably easy one-electron reduction of 16-electron molybdenum nitrosyls: mechanistic implications for the formation of alkoxy, amido, hydrazido, and thiolato complexes containing the tris-3,5-dimethylpyrazolylborato-ligandJournal of the Chemical Society, Chemical Communications, 1981