Electron-deficient groupIVmetal alkyl cations, and the synthesis of Zr(CH2Ph)3(η6-C6H5)BPh3: a fluxional arene π-complex of a d0metal
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1038-1039
- https://doi.org/10.1039/c39900001038
Abstract
Mild protolysis of titanium and zirconium alkyls provides a general route to solvent or anion stabilised 6- and 10-electron cationic group IV alkyl complexes, including the first halide-free arene complex of a d0 metal.Keywords
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