Mechanism for Electron-Transfer Induced Isomerization of Stilbene as Studied by Magnetic Field Effects
- 1 February 1989
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 18 (2) , 251-254
- https://doi.org/10.1246/cl.1989.251
Abstract
External magnetic field effects and laser flash photolysis were applied to elucidating the mechanism of dicyanoanthracene-sensitized isomerization of stilbene in acetonitrile, indicating that the stilbene cation radical is a key intermediate for isomerization. Sensitizer dependence of the isomerization efficiency is discussed in terms of the rate of back electron transfer in singlet radical pairs.This publication has 12 references indexed in Scilit:
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