Conjugate addition of the phenyldimethylsilyl group to αβ-unsaturated carbonyl compounds using a silylzincate in place of the silylcuprate
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 6,p. 701-706
- https://doi.org/10.1039/p19940000701
Abstract
Lithium phenyldimethylsilyl(dialkyl)zincates add to a number of αβ-unsaturated carbonyl compounds to give, in most cases, higher yields of the conjugate addition product than we had achieved with the corresponding silylcuprate.Keywords
This publication has 28 references indexed in Scilit:
- Direkte Michael‐artige Addition von Si‐Gruppen an β‐Aryl‐α,β‐ungesättigte Carbonylverbindungen mit R3SiCl/Bu2Cu(CN)Li2European Journal of Inorganic Chemistry, 1990
- Diastereofacial selectivity in Diels–Alder reactions of a diene having a stereogenic centre carrying a silyl group adjacent to the diene systemJournal of the Chemical Society, Perkin Transactions 1, 1989
- Carbonium ion rearrangements controlled by the presence of a silyl groupJournal of the Chemical Society, Perkin Transactions 1, 1989
- A regiocontrolled synthesis of allylstannanesJournal of the Chemical Society, Perkin Transactions 1, 1987
- Diastereoselective aldol reactions of β-silylenolates: a formal synthesis of thienamycinJournal of the Chemical Society, Chemical Communications, 1986
- A synthesis of allylsilanes in which the silyl group is at the more-substituted end of the allyl groupJournal of the Chemical Society, Perkin Transactions 1, 1984
- Controlling the outcome of a carbocation-initiated cyclisationJournal of the Chemical Society, Perkin Transactions 1, 1984
- The Utility of Phosphonate Carbanions in Olefin SynthesisJournal of the American Chemical Society, 1961
- Preparation of Silyl- and Germylmetallic CompoundsJournal of the American Chemical Society, 1960
- Ueber BenzalpinakolinEuropean Journal of Inorganic Chemistry, 1897