Self‐Assembly of Organodiphosphonate, Polyoxomolybdate and Diphenanthrolinecobalt(II) into Two Clusters and One Linear Polymer
- 28 April 2003
- journal article
- research article
- Published by Wiley in European Journal of Inorganic Chemistry
- Vol. 2003 (9) , 1798-1801
- https://doi.org/10.1002/ejic.200200678
Abstract
[{Co(1,10‐phen)2}2{(Mo4O12)(O3PCH2CH2PO3)}·(H2O)] (1), [{Co(1,10‐phen)2}2{(Mo4O12)(O3PCH2CH2CH2PO3)}·(1.5H2O)] (2) and [{Co(1,10‐phen)2(H2O)2}{Co(1,10‐phen)2(H2O)}{(Mo5O15)(O3PCH2CH2CH2CH2PO3)}·(6H2O)] (3) were synthesized by self‐assembly of H2O3P(CH2)nPO3H2 (n = 2−4), polyoxomolybdate and [Co(1,10‐phen)2]2+ (1,10‐phen = 1,10‐phenanthroline) under hydrothermal conditions. Compounds 1 and 2 are novel heterometallic hexanuclear clusters, while compound 3 is a new linear polymer. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)Keywords
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