Phosphine–olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes
- 21 July 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 37 (32) , 3408-3410
- https://doi.org/10.1039/b608129k
Abstract
Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine–olefin complexes, some of which are catalytically active for 1,4-additions.Keywords
This publication has 24 references indexed in Scilit:
- Synthesis, Neutron Structure, and Reactivity of the Bis(dihydrogen) Complex RuH2(η2-H2)2(PCyp3)2 Stabilized by Two TricyclopentylphosphinesJournal of the American Chemical Society, 2005
- Chiral Phosphine–Olefin Bidentate Ligands in Asymmetric Catalysis: Rhodium‐Catalyzed Asymmetric 1,4‐Addition of Aryl Boronic Acids to MaleimidesAngewandte Chemie International Edition in English, 2005
- Olefins as Steering Ligands for Homogeneously Catalyzed HydrogenationsChemistry – A European Journal, 2004
- Rhodium-Catalyzed Asymmetric 1,4-Addition and Its Related Asymmetric ReactionsChemical Reviews, 2003
- High-Resolution EPR Spectroscopic Investigations of a Homologous Set of d9-Cobalt(0), d9-Rhodium(0), and d9-Iridium(0) ComplexesChemistry – A European Journal, 2002
- Alkane C–H activation and functionalization with homogeneous transition metal catalysts: a century of progress—a new millennium in prospectJ. Chem. Soc., Dalton Trans., 2001
- Iridium PCP pincer complexes: highly active and robust catalysts for novel homogeneous aliphatic dehydrogenationsChemical Communications, 1999
- Dibenzotropylidene phosphanes (TROPPs): synthesis and coinage metal complexesNew Journal of Chemistry, 1998
- Versatile Reactivity of the Bis(dihydrogen) Complex RuH2(H2)2(PCy3)2 toward Functionalized Olefins: Olefin Coordination versus Hydrogen Transfer via the Stepwise Dehydrogenation of the Phosphine LigandOrganometallics, 1996
- Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous SolutionAccounts of Chemical Research, 1995