Structure and internal rotation of H2O–CO2, HDO–CO2, and D2O–CO2 van der Waals complexes
- 15 March 1984
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 80 (6) , 2439-2445
- https://doi.org/10.1063/1.446993
Abstract
The radio frequency and microwave spectra of H2O–CO2, HDO–CO2, and D2O–CO2 have been measured by molecular beam electric resonance spectroscopy. Rotational constants, deuterium quadrupole coupling constants, and dipole moments are reported.Keywords
This publication has 19 references indexed in Scilit:
- Ab initio molecular orbital calculations on the water-carbon dioxide system: carbonic acidPublished by Elsevier ,2001
- The microwave spectrum and molecular structure of CO2–HClThe Journal of Chemical Physics, 1982
- Stopped-flow studies of carbon dioxide hydration and bicarbonate dehydration in water and water-d2. Acid-base and metal ion catalysisJournal of the American Chemical Society, 1977
- Ab initio molecular orbital calculations on the water-carbon dioxide system: Molecular complexesChemical Physics Letters, 1975
- Electric Resonance Spectroscopy of Hypersonic Molecular BeamsThe Journal of Chemical Physics, 1972
- Solubility of water in compressed carbon dioxide, nitrous oxide, and ethane. Evidence for hydration of carbon dioxide and nitrous oxide in the gas phaseJournal of the American Chemical Society, 1971
- Vibrational Relaxation in CO2/D2O MixturesThe Journal of the Acoustical Society of America, 1968
- Internal Rotation in Completely Asymmetric Molecules. III. Theory for Molecules with Twofold Potential BarriersThe Journal of Chemical Physics, 1967
- Vibrational Relaxation in Carbon Dioxide/Water-Vapor MixturesThe Journal of the Acoustical Society of America, 1965
- Microwave spectrum of nitramideJournal of Molecular Spectroscopy, 1963