The influence of CT states and energy transfer on the luminescence of Ln2[Pt(CN)4]3⋅yH2O single crystals
- 1 September 1982
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 77 (5) , 2266-2272
- https://doi.org/10.1063/1.444149
Abstract
Time resolved emission measurements of Ln2[Pt(CN)4]3⋅yH2O single crystals (LnCP) at T = 1.9 K are reported. The time dependence of the E⊥c polarized emission of these crystals—with the exception of LuCP—deviates considerably from that of other tetracyanoplatinates (MCP, M≠Ln). The results can be explained assuming an admixture of (Ln, 4f) orbitals to the emitting Pt‐complex states (Pt, 5dz2).Keywords
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