The Synthesis and Complex Formatirn of Stererisomers of some new α-Dioximes
- 1 January 1981
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 11 (7) , 621-631
- https://doi.org/10.1080/00945718108056007
Abstract
Two new α-dioximes, 1,4-diphenyl-2,3-bis(hydroxyimino)-piperazine, DBPH2, and bis(α-mercaptopyridyl)glyoxime, BMGH2, and their stereoisomers have been isolated. Their complexes with various transition metal ions have been synthesized. The transformation of the amphi-DBPNi(II) complex to anti-form has been investigated. The structures of all isolated compounds were proposed on the basis of analyses, i.r. and u.v-visible data.Keywords
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