Electrostatic crystal-field contributions in rare-earth compounds with consistent multipolar effects. II. Contribution to-odd parameters (transition probabilities)
- 15 June 1983
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 27 (12) , 7386-7392
- https://doi.org/10.1103/physrevb.27.7386
Abstract
-odd electrostatic crystal-field parameters () involved in the Judd-Ofelt theory of electronic transitions within the configuration are computed including contributions of point charges, consistent dipoles, and quadrupoles induced in a crystalline lattice (calculated and experimental intensity parameters are compared). The coefficients () involved in the pseudo-multipolar-field theory are also computed for 14 rare-earth or rare-earth—doped compounds (i.e., for LiY: , YOBr, and YOCl: ; BaFCl and SrFCl: ; BaTi: , NdAl, and LaAl: ; , S, La, and La: ; and K : ). The contribution of to transition rates is evaluated for the and
Keywords
This publication has 16 references indexed in Scilit:
- Electrostatic crystal-field contributions in rare-earth compounds with consistent multipolar effects. I. Contribution to-even parametersPhysical Review B, 1982
- Some theoretical investigations in crystal field theoryMolecular Physics, 1979
- Dynamic coupling contributions to the intensity of hypersensitive lanthanide transitionsChemical Physics Letters, 1974
- Probabilities for radiative and nonradiative decay of Pr3+ion in LaAlO3Journal of Physics C: Solid State Physics, 1973
- Sternheimer Shielding-Antishielding; Rare-Earth IonsPhysical Review A, 1973
- Crystal-Field Shielding Parameters forandPhysical Review B, 1970
- Probabilities for Radiative and Nonradiative Decay ofin LaPhysical Review B, 1967
- Optical Absorption and Fluorescence Intensities in Several Rare-Earth-Doped and La Single CrystalsPhysical Review B, 1966
- Hypersensitive pseudoquadrupole transitions in lanthanidesMolecular Physics, 1964
- Optical Absorption Intensities of Rare-Earth IonsPhysical Review B, 1962