Synthesis, reactivity and X-ray crystallographic characterization of chloro(propan-2-ol)bis(tetraisopropoxoaluminato)praseodymium(III) dimer, [{Pr[Al(OPri)4]2(PriOH)(µ-Cl)}2]
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 152-153
- https://doi.org/10.1039/c39920000152
Abstract
The product of the 1 : 2 reaction between PrCl3·3PriOH and K[Al(OPri)4] in benzeno–propan-2-ol, has been shown by X-ray crystallographic analysis to be a heptacoordinated heteroleptic alkoxometallatopraseodymium(III) complex 1, which affords solvated and unsolvated species respectively by ligand displacement reactions and distillation in vacuo.Keywords
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