Cyclopalladated and cycloplatinated complexes of 6-phenyl-2,2′-bipyridine: platinum-platinum interactions in the solid state
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 513-515
- https://doi.org/10.1039/c39900000513
Abstract
The crystal and molecular structures of the complexes [PdLCl] and [PtL(MeCN)][PF6](HL = 6-phenyl-2,2′-bipyridine) have been determined; in each case, the cyclometallated ligand behaves as a terdentate C,N,N-donor, analogous to 2,2′:6′,2″-terpyridine; in the case of the platinum complex metal–metal interactions are observed, giving rise to alternate long–short contacts [3.28(1), 4.59(1)Å] between canons.Keywords
This publication has 9 references indexed in Scilit:
- Cyclometallation reactions of 6-phenyl-2,2′-bipyridine; a potential C,N,N-donor analogue of 2,2′: 6′,2″-terpyridine. Crystal and molecular structure of dichlorobis(6-phenyl-2,2′-bipyridine)ruthenium(II)J. Chem. Soc., Dalton Trans., 1990
- The direct cycloauration of 6(2″-thienyl)2-2′-bipyridineJournal of Organometallic Chemistry, 1989
- Different bonding modes for 6-(2-thienyl)-2,2′-bipyridine at ruthenium (II); the structural characterisation of [Ru(HL)(HL)Cl][BF4][HL=6-(2-thienyl)-2,2′-bipyridine]Journal of the Chemical Society, Chemical Communications, 1989
- Temperature dependence of the luminescence of cyclometalated palladium(II), rhodium(III), platinum(II), and platinum(IV) complexesInorganic Chemistry, 1988
- Dual emission from an ortho-metalated iridium(III) complexJournal of the American Chemical Society, 1987
- cis-Bis(2-phenylpyridine)platinum(II) (CBPPP): a simple molecular platinum compoundInorganic Chemistry, 1984
- Cyclometallated complexes incorporating a heterocyclic donor atom; the interface of coordination chemistry and organometallic chemistryPolyhedron, 1984
- cis‐Bis(2‐Phenylpyridine)platinum(II) (CBPPP). A simple molecular platinum compound preliminary communicationHelvetica Chimica Acta, 1983
- The Chemistry of Complexes Containing 2,2′-Bipyridyl, 1, 10-Phenanthroline, or 2,2′,6′,2”-Terpyridyl as LigandsPublished by Elsevier ,1970