Electronic energy level and intensity correlations in the spectra of the trivalent actinide aquo ions. II. Cm3+
- 15 October 1975
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 63 (8) , 3510-3514
- https://doi.org/10.1063/1.431789
Abstract
The free‐ion energy level scheme of Cm3+ (aquo) to ∼40 000 cm−1 was determined. Energy level assignments were made based on the correlation between observed band intensities and those calculated using the Judd–Ofelt theory. Use of an expanded set of effective operators provided the basis for computation of free‐ion energies in good agreement with the experimental assignments.Keywords
This publication has 17 references indexed in Scilit:
- Electronic energy level and intensity correlations in the spectra of the trivalent actinide aquo ions. I. Es3+The Journal of Chemical Physics, 1973
- Absorption spectrum of CfCl3The Journal of Chemical Physics, 1973
- Determination of the half-lives of 246Cm and 248Cm by absolute specific activity techniquesJournal of Inorganic and Nuclear Chemistry, 1971
- Spectral Intensities of the Trivalent Lanthanides and Actinides in Solution. II. Pm3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, and Ho3+The Journal of Chemical Physics, 1968
- Alpha half-life of 244CmJournal of Inorganic and Nuclear Chemistry, 1968
- Lanthanide and Actinide Absorption Spectra in SolutionPublished by American Chemical Society (ACS) ,1967
- Optical Spectra of Tripositive Curium−244 in Lanthanum TrichlorideThe Journal of Chemical Physics, 1966
- Intensities of Crystal Spectra of Rare-Earth IonsThe Journal of Chemical Physics, 1962
- Optical Absorption Intensities of Rare-Earth IonsPhysical Review B, 1962
- A Study of the Complexes of Curium(III) by Absorption Spectrometry1Journal of the American Chemical Society, 1959