A large rhodium carbonyl cluster compound containing four encapsulated nitrogen atoms: synthesis and X-ray structure of the anion [Rh23N4(CO)20(µ-CO)18]3–
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 19,p. 1405-1406
- https://doi.org/10.1039/c39920001405
Abstract
The novel anion [Rh23N4(CO)20(µ-CO)18]3–, obtained by controlled pyrolysis of [Rh6N(CO)15]–, contains a large metallic polyhedron of idealized C2 symmetry, which has 21 surface metals and encloses a couple of bonded rhodium atoms and four interstitial nitrogen atoms, each connected to five rhodium atoms.Keywords
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