MBE of Magnetic Metallic Structures

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Abstract
Epitaxial growth of magnetic metals actually pre-dates epitaxial growth of semiconductors. The earliest work (1936), which reported single-crystal Fe growth on NaCl, exploited the fact that single-crystal substrates of NaCl were easy to obtain, readily cleaved, and could be cleaned in a vacuum by heating. The good lattice match between the two systems and lack of interfacial disruption upon growth permitted excellent quality single-crystal films of Fe to be grown in relatively modest vacuum. Improved vacuum techniques broadened the range of materials which could be studied, with respect to both the films and substrates. The most recent ultrahigh vacuum (UHV) techniques developed for molecular beam epitaxial growth of semiconductors, including the large array of electron-based analytical tools, have also been exploited to grow and characterize magnetic metal films.Some requirements for these magnetic materials, such as the need for higher temperature effusion sources to generate useful fluxes of Fe, Co and Ni, and high vacuum in the presence of e-beam sources in order to avoid oxidation of the rare earths, served to stimulate new technical developments for the field in general. It is now possible to control growth to a fraction of a monolayer (ML) and even to know when one ML coverage is complete and another is beginning. The techniques have become so successful that a whole new subfield of magnetism has emerged — surface and interfacial magnetism — in which the work would be largely meaningless if one could not grow precisely characterized epitaxial magnetic metal films. Recent work has shown that it is now possible to grow single-crystal magnetic metal films on a wide variety of substrates, including insulators (oxides and salts), semiconductors, and metals.