Open-tube Zn diffusion in GaAs using diethylzinc and trimethylarsenic: Experiment and model

Abstract
We have characterized the diffusion of Zn into GaAs from the organometallic sources diethylzinc and trimethylarsenic. This method produces surface hole concentrations in excess of 1020 cm−3 with good control of junction depths as shallow as 0.1 μm. Smooth surface morphology is retained. The profile shape is much more complex than the accepted interstitial-substitutional Zn-diffusion model would predict. To explain the observed profiles, a new model for Zn diffusion is proposed and implemented in a computer simulation.

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