Abstract
Float-zone silicon doped with carbon (1.6*1017Cm-3) has been irradiated with 2 MeV electrons below 220 K up to a dose of 1.9*1018 electrons cm-2 leading to a monotonic decrease in the concentration of the substitutional impurity. Interstitial carbon is produced but its concentration saturates and then falls because the defects trap mobile self interstitials. New infrared absorption lines at 966 and 959 cm-1 (77 K) are ascribed to a C1-Sii pair defect which also acts as a nucleation site for agglomeration of Si1 atoms. The latter reactions appear to occur during irradiations at 300 K.