Syntheses and1H-NMR Studies on Mucin-Type Sugars Chirally Deuterated at the C-6 Position
- 1 December 1988
- journal article
- research article
- Published by Taylor & Francis in Journal of Carbohydrate Chemistry
- Vol. 7 (4) , 711-731
- https://doi.org/10.1080/07328308808058940
Abstract
1-O-Methyl analogs of mucin oligosaccharide components, D-GalNAc (1a and 1b). β-D-Galp-(1-3)-D-GalNAc (2) and β-D-Galp(1-3)-[β-D-GlcNAc-(1-6)]-D-GalNAc (3) in which the H-6proS proton was selectively replaced by a deuterium, were synthesized to study the solution conformations about the C5-C6 fragments by 1H-NMR spectroscopy. The study revealed the preference of the gt-conformer for these sugars.This publication has 19 references indexed in Scilit:
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