Infrared Dispersion in Binary Mixtures of Benzene, Carbon Tetrachloride, and Carbon Disulfide
- 15 November 1972
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 57 (10) , 4370-4374
- https://doi.org/10.1063/1.1678077
Abstract
The integrated intensities of the infrared‐active fundamental bands of binary mixtures of C6H6, C6D6, CCl4, and CS2 were determined in the 3500–400‐cm−1 range, using the dispersion method. It was found that deviations of band intensity in these systems from those predicted from gas‐phase measurements are most likely due to ``physical interactions'' which perturb vibrational states rather than due to ``chemical interactions'' which perturb the ground electronic state of the absorbing molecule.Keywords
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