Effects of As/P exchange reaction on the formation of InAs/InP quantum dots

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Abstract
InAs self-assembled quantum dots (SAQDs) were grown on InP at various temperatures and V/III ratios by metalorganic chemical vapor deposition. The density, size distribution, and shape of the InAs SAQDs changed significantly with temperature and V/III ratio. Careful analysis of the total volume of the dots grown at various conditions showed that the volume far exceeded the amount of deposition supplied from the gas-phase sources. The amount of excess InAs and the aspect ratio (height/lateral size) of the SAQD increased with temperature and V/III ratio, strongly suggesting that the As/P exchange reaction at the surface played an important role in the kinetics of SAQD formation. Insertion of a lattice-matched InGaAs buffer layer suppressed the excess InAs formation, and lowered the aspect ratio, confirming the effect of the As/P exchange reaction.