Limitations on stress compensation in AlxGa1 −xAs1−yPy–GaAs LPE layers

Abstract
It has been shown previously that the room‐temperature lattice mismatch between GaAs and AlxGa1−xAs may be reduced by the incorporation of small amounts of phosphorus in the alloy. By measuring the curvature of thin (2 μ) freely suspended foils of AlxGa1−xAs1−yPy grown by LPE, we have determined the gradient in the lattice parameter in foils which have been substantially stress‐compensated. This gradient is caused by depletion of aluminum and phosphorus from the melt during growth. Such depletion limits the extent to which this stress‐compensating technique may be applied to the growth of GaAs heterostructure lasers. Present results imply that stress reductions of about a factor of 10 may be obtained for 2‐μ quaternary layers, although greater factors are achievable for thinner layers.

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