Polycrystalline silicon formed by ultrahigh-vacuum sputtering system

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Abstract
Using an ultrahigh‐vacuum (UHV) sputtering system, we could grow two new methods of polycrystalline silicon films. The one is as‐deposited polycrystalline silicon on glass at substrate temperatures under 500 °C. The other is solid‐phase‐crystallization by thermal annealing of as‐deposited amorphous silicon films in a UHV. As‐deposited polycrystalline silicon films were oriented to (220) and grain sizes were determined from half‐width of x‐ray diffraction to be about 40 nm. From the deposition temperature dependence of the x‐ray diffraction peak intensity, the activation energy of the crystalline growth was calculated to be about 0.6 eV. Hydrogen atoms in the sputtering gas lower the reproducibility of as‐deposited poly‐Si. Polycrystalline silicon films produced by thermal annealing of as‐deposited amorphous silicon films at 550 °C in UHV have a (111) orientation. Field‐effect mobilities of the as‐deposited polycrystalline silicon film and the polycrystalline silicon film by UHV thermal annealing were 5 and 18 cm2/V s, respectively.